Q.

At 27 Co in presence of a catalyst, activation energy of a reaction is lowered by 10 kJ mol-1. The logarithm of ratio of k(catalysed)k(uncatalysed) is...
(Consider that the frequency factor for both the reactions is same)           [2026]

1 3.482  
2 17.41  
3 1.741  
4 0.1741  

Ans.

(3)

KcatalystKuncatalyst=eΔEaRT

ln(KcatalystKuncatalyst)=ΔEaRT

log(KcatalystKuncatalyst)=ΔEa2.303RT

=10×10002.303×8.314×300

log(KcatalystKuncatalyst)=1.741