Q.

Assume that a drop of liquid evaporates by decrease in its surface energy, so that its temperature remains unchanged. What should be the minimum radius of the drop for this to be possible The surface tension is T, density of liquid is ρ and L is its latent heat of vaporization.          [2012]

1 ρLT  
2 TρL  
3 TρL  
4 2TρL  

Ans.

(4)

When radius is decreased by ΔR,

Decrease in surface energy = Heat lost as latent heat

(4πR2ΔRρ)L=4π[R2-(R-ΔR)2]T

  ρR2ΔRL=T[R2-R2+2RΔR-ΔR2]

  ρR2ΔRL=T(2RΔR)    [ΔR is very small]

  R=2TρL