Q.

An electron in an excited state of Li2+ ion has angular momentum 3h2π. The de Broglie wavelength of the electron in this state is pπa0 (where a0 is the Bohr radius). The value of p is                            [2015]


Ans.

(2)

Angular momentum, L=mvr=nh2π=3h2π⇒n=3

∵  λ=hp=hmv=hrmvr⇒mvr=hrλ        ∴ hrλ=3h2π

∴  λ=2πr3=23π[a0n2z]      [∵r=a0n2z]

∴  λ=23πa0[3×33]=2πa0     [∵n=3, z=3]

∴  p=2