Aluminium chloride in acidified aqueous solution forms a complex ‘A’, in which hybridisation state of Al is ‘B’. What are ‘A’ and ‘B’, respectively? [2019]

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Solution

Q.
Aluminium chloride in acidified aqueous solution forms a complex ‘A’, in which hybridisation state of Al is ‘B’. What are ‘A’ and ‘B’, respectively [2019]

1 ${[Al {(H_{2} O)}_{6}]}^{3 +}, s p^{3} d^{2}$

2 ${[Al {(H_{2} O)}_{4}]}^{3 +}, s p^{3}$

3 ${[Al {(H_{2} O)}_{4}]}^{3 +}, d s p^{2}$

4 ${[Al {(H_{2} O)}_{6}]}^{3 +}, d^{2} s p^{3}$

Ans.
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