Q.

A Hydrogen-like atom has atomic number Z. Photons emitted in the electronic transitions from level n=4 to level n=3 in these atoms are used to perform photoelectric effect experiment on a target metal. The maximum kinetic energy of the photoelectrons generated is 1.95 eV. If the photoelectric threshold wavelength for the target metal is 310 nm, the value of Z is ______.                             [2023]

[Given: hc = 1240 eV–nm and Rhc = 13.6 eV, where R is the Rydberg constant, h is Planck's constant and c is the speed of light in vacuum.]


Ans.

(3)

Kmax=E-W⇒E4→3=Kmax+W=1.95+hcλ

=1.95+1240310=5.95 eV

13.6Z2(132-142)=5.95

13.6Z2(79×16)=5.95

⇒Z2=5.95×9×1613.6×7=9

∴ Z=3