Q.

Which will make basic buffer                                          [2019]

1 100 mL of 0.1 M HCl + 100 mL of 0.1 M NaOH  
2 50 mL of 0.1 M NaOH + 25 mL of 0.1 M CH3COOH  
3 100 mL of 0.1 M CH3COOH + 100 mL of 0.1 M NaOH  
4 100 mL of 0.1 M HCl + 200 mL of 0.1 M NH4OH   

Ans.

(4)

Acid-base titration:

HCl10 mmol+NH4OH20 mmolNH4Cl

   HCl is the limiting reagent.

Solution contains NH4OH (weak base) and NH4Cl (salt of strong acid and weak base). Therefore, a basic buffer will be formed.