Q.

Which amongst the following is incorrect statement           [2022]

1 The bond orders of O2+,O2,O2- and O22- are 2.5, 2, 1.5 and 1, respectively.  
2 C2 molecule has four electrons in its two degenerate π molecular orbitals.
 
3 H2+ ion has one electron.
 
4 O2+ ion is diamagnetic.  

Ans.

(4)

O2+ :σ1s2σ*1s2σ2s2σ*2s2σ2pz2π2px2=π2py2π*2px1

Due to the presence of one unpaired electron, O2+ is paramagnetic in nature.