Q.

What amount of bromine will be required to convert 2 g of phenol into 2,4,6-tribromophenol :

(Given molar mass in g mol-1 of C, H, O, Br are 12, 1, 16, 80 respectively)                    [2025]

1 6.0 g  
2 20.44 g  
3 10.22 g  
4 4.0 g  

Ans.

(3)

Moles of phenol=Given massMolar mass=294mol

By stoichiometry of the reaction,

Moles of Br2=3×Moles of phenol=3×294mol

Mass of bromine=Moles of Br2×Molar mass of Br2

Mass of bromine=3×294 mol×160 g mol-1=10.21 g