Q.

The standard enthalpy and standard entropy of decomposition of N2O4 to NO2 are 55.0 kJ mol-1 and 175.0 J/K/mol respectively. The standard free energy change for this reaction at 25°C in J mol-1 is _____ (Nearest integer).                     [2025]


Ans.

(2850)

ΔG°=ΔH°-TΔS°

ΔG°=55kJ mol-1-298K×175JK-1mol-1

ΔG°=55000J mol-1-298K×175JK-1mol-1

ΔG°=55000J mol-1-52150J mol-1 

ΔG°=2850J mol-1