Q.

The number of species from the following which are paramagnetic and with bond order equal to one is ________ .

H2,He2+,O2+,N22-,O22-,F2,Ne2+,B2                    [2024]


Ans.

(1)

Only B2.

Molecule Electronic configuration Number of unpaired electrons
H2 σ1s2
(diamagnetic)
12×(2-0)=1
He2+ σ1s2,σ*1s1
(paramagnetic)
12×(2-1)=0.5
O2+ σ1s2,σ*1s2,σ2s2,σ*2s2,σ2pz2,π2px2,π2py2,π*2px1
(paramagnetic)
12×(10-5)=2.5
N22- σ1s2,σ*1s2,σ2s2,σ*2s2,π2px2,π2py2,σ2pz2,π*2px2
(diamagnetic)
12×(10-6)=2
O22- σ1s2,σ*1s2,σ2s2,σ*2s2,σ2pz2,π2px2,π2py2,π*2px2,σ*2py2
(diamagnetic)
12×(10-8)=1
F2 σ1s2,σ*1s2,σ2s2,σ*2s2,σ2pz2,π2px2,π2py2,π*2px2,π*2py2
(diamagnetic)
12×(10-8)=1
Ne2+ σ1s2,σ*1s2,σ2s2,σ*2s2,σ2pz2,π2px2,π2py2,π*2px2,π*2py2,σ*2pz1
(paramagnetic)
12×(10-9)=0.5
B2 σ1s2,σ*1s2,σ2s2,σ*2s2,π2px1,π2py1
(paramagnetic)
12×(6-4)=1