The heat of combustion of solid benzoic acid at constant volume is –321.30 kJ at 27°C. The heat of combustion at constant pressure is (–321.30 – R) kJ, the value of x is

STUDY MATERIALS
COURSES
MORE
SUCCESS STORY
ADMISSION
STORE

Back

JEE ADVANCE

CLASS XI - XII
CRASH COURSE

CLASS XI - XII

CRASH COURSE

JEE MAIN

CLASS XI - XII
CRASH COURSE

CLASS XI - XII

CRASH COURSE

NEET

CLASS XI - XII
CRASH COURSE

CLASS XI - XII

CRASH COURSE

BITSAT

CLASS XI - XII

CLASS XI - XII

CBSE BOARD

CLASS IX

CLASS X

CLASS XI

CLASS XII

CLASS VI

CLASS VII

CLASS VIII

UP BOARD

CLASS IX
CLASS X
CLASS XI
CLASS XII

CLASS IX

CLASS X

CLASS XI

CLASS XII

CUET

CRASH COURSE

CRASH COURSE

Courses

CLASSROOM COURSES
ONLINE COURSES

ONLINE COURSES

More

Solution

Q.
The heat of combustion of solid benzoic acid at constant volume is –321.30 kJ at 27°C. The heat of combustion at constant pressure is (–321.30 – $x$ R) kJ, the value of $x$ is _________ . [2024]

Ans.
(150)

$C_{6} H_{5} COOH (s) + \frac{15}{2} O_{2} (g) \to 7 {CO}_{2} (g) + 3 H_{2} O (l)$

$Δ n_{g} = Gaseous moles of products - Gaseous moles of reactants$

$= 7 - 7.5 = - 0.5$

$Heat of combustion at constant pressure (Δ H) is related to heat of combustion at constant volume (Δ U) by :$

$Δ H = Δ U + Δ n_{g} R T$

$Δ H = - 321.3 - 0.5 R \times 300$

$Δ H = - 321.3 - 150 R$

Want Us to Email you About Special Offers & Updates?