Q.

The de-Broglie's wavelength of an electron in the 4th orbit is _________ πa0. (a0 = Bohr's radius)               [2024]


Ans.

(8)            De-Broglie's wavelength (λ) is related to mass (m) and velocity v of electron by:

                λ=hmv-I, where h is Planck's constant.

               By quantization of angular momentum:

               mvr=nh2π-II

               Where n is orbit number and r is radius of nth orbit.

               Rearranging equation II

               2πr=nhmv-III

               From I and III

                2πr=nλ-IV

               Radius (r) of nth orbit is related to radius of first orbit (a0) as:

               r=a0n2Z-V

               From IV and V:

               2πa0n2Z=nλ

               λ=2πa0nZ

               Taking atom to be H, Z = 1 and for fourth orbit, n = 4

                λ=2πa041=8πa0