The correct order of acidic strength of the major products formed in the given reactions, is:

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Solution

Q.
The correct order of acidic strength of the major products formed in the given reactions, is: [2026]

A. $PhN H_{2} \begin{matrix} \overset{(1) {NaNO}_{2} + HCl (< 5 ° C)}{\to} [A] \\ (2) CuCN] \\ (3) H_{3} O^{+} / Δ \end{matrix}$

B. ${CH}_{3} {CH}_{2} CHO \to_{Δ}^{{[Ag {({NH}_{3})}_{2}]}^{+}, {OH}^{-}} [B]$

C. ${CH}_{4} + O_{2} \begin{matrix} \overset{(i) {Mo}_{2} O_{3}}{\to} [C] \\ (ii) {Na}_{2} {Cr}_{2} O_{7} / H^{+} \end{matrix}$

D. ${PhCH}_{2} MgBr + C O_{2} \begin{matrix} \overset{Dry ether}{\to} [D] \\ H_{3} O^{+} \end{matrix}$

Choose the correct answer from the options given below:

1 A > D > B > C

2 C > A > D > B

3 A > D > C > B

4 C > B > A > D

Ans.
(2)

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