Q.

The correct decreasing order of spin only magnetic moment values (B.M.) of Cu+, Cu2+, Cr2+ and Cr3+ ions is :       [2025]

1 Cu+>Cu2+>Cr3+>Cr2+  
2 Cu2+>Cu+>Cr2+>Cr3+  
3 Cr2+>Cr3+>Cu2+>Cu+  
4 Cr3+>Cr2+>Cu+>Cu2+  

Ans.

(3)

Ion Electronic configuration Number of unpaired electrons (n) Spin only magnetic moment (μ)=n(n+2) BM
Cu+ [Ar]183d10 0 0
Cu2+ [Ar]183d9 1 1(1+2)BM=3BM
Cr2+  [Ar]183d4 4 4(4+2)BM=24BM
Cr3+ [Ar]183d3 3 3(3+2)BM=15BM

 

Thus, the decreasing order of spin-only magnetic moment is: Cr2+>Cr3+>Cu2+>Cu+