Q.

The activation energy of a reaction can be determined from the slope of which of the following graphs           [2015]

1 lnk vs 1T  
2 Tlnk vs 1T  
3 lnk vs T  
4 lnkT vs T  

Ans.

(1)

According to Arrhenius equation,

k=Ae-Ea/RT

lnk=lnA-EaRT

Hence, if ln k is plotted against 1/T, slope of the line will be -EaR.