Q.

Steam at 100°C is passed into 20 g of water at 10°C. When water acquires a temperature of 80°C, the mass of water present will be [Take specific heat of water = 1 cal g-1 °C-1 and latent heat of steam = 540 cal g-1]               [2014]

1 24 g  
2 31.5 g  
3 42.5 g  
4 22.5 g  

Ans.

(4)

Here,

Specific heat of water, sw=1 cal g-1°C-1

Latent heat of steam, Ls=540 cal g-1

Heat lost by m g of steam at 100oC to change into water at 80°C is

Q1=mLs+mswΔTw

      =m×540+m×1×(100-80)

       =540m+20m=560m

Heat gained by 20 g of water to change its temperature from 10°C to 80°C is

         Q2=mwswΔTw=20×1×(80-10)=1400

According to the principle of calorimetry, Q1=Q2

   560m=1400    m=2.5 g

Total mass of water present

          =(20+m)g=(20+2.5)g=22.5 g