Statement I: PF and BrF both exhibit sp³d hybridisation.

STUDY MATERIALS
COURSES
MORE
SUCCESS STORY
ADMISSION
STORE

Back

JEE ADVANCE

CLASS XI - XII
CRASH COURSE

CLASS XI - XII

CRASH COURSE

JEE MAIN

CLASS XI - XII
CRASH COURSE

CLASS XI - XII

CRASH COURSE

NEET

CLASS XI - XII
CRASH COURSE

CLASS XI - XII

CRASH COURSE

BITSAT

CLASS XI - XII

CLASS XI - XII

CBSE BOARD

CLASS IX

CLASS X

CLASS XI

CLASS XII

CLASS VI

CLASS VII

CLASS VIII

UP BOARD

CLASS IX
CLASS X
CLASS XI
CLASS XII

CLASS IX

CLASS X

CLASS XI

CLASS XII

CUET

CRASH COURSE

CRASH COURSE

Courses

CLASSROOM COURSES
ONLINE COURSES

ONLINE COURSES

Q.
Given below are two statements:
Statement I: ${PF}_{5}$ and ${BrF}_{5}$ both exhibit ${sp}^{3} d$ hybridisation.
Statement II: Both ${SF}_{6}$ and ${[Co {({NH}_{3})}_{6}]}^{3 +}$ exhibit ${sp}^{3} d^{2}$ hybridisation.

In the light of the above statements, choose the correct answer from the options given below: [2024]

1 Statement I is true but Statement II is false

2 Both Statement I and Statement II are false

3 Both Statement I and Statement II are true

4 Statement I is false but Statement II is true

Ans.
(2)

s and p block elements with C.N. = 6 exhibit ${sp}^{3} d^{2}$ hybridization.

${[Co({NH}_{3})_{6}]}^{3 +}$

Oxidation number of Co = +3

${Co}^{3 +} =$ ${}_{18}[Ar]$ $3 d^{6}$

${Co}^{3 +} complexes with CN = 6 split as t_{2 g}^{2, 2, 2} e_{g}^{0, 0} and undergo d^{2} s p^{3} hybridization.$

Solution

1 Statement I is true but Statement II is false

2 Both Statement I and Statement II are false

3 Both Statement I and Statement II are true

4 Statement I is false but Statement II is true

Want Us to Email you About Special Offers & Updates?

Solution

Q. Given below are two statements: Statement I: PF5 and BrF5 both exhibit sp3d hybridisation. Statement II: Both SF6 and [Co(NH3)6]3+ exhibit sp3d2 hybridisation. In the light of the above statements, choose the correct answer from the options given below: [2024]

1 Statement I is true but Statement II is false

2 Both Statement I and Statement II are false

3 Both Statement I and Statement II are true

4 Statement I is false but Statement II is true

Ans. (2) s and p block elements with C.N. = 6 exhibit sp3d2 hybridization. [Co(NH3)6]3+ Oxidation number of Co = +3 Co3+=[18Ar]3d6 Co3+ complexes with CN = 6 split as t2g2,2,2 eg0,0 and undergo d2sp3 hybridization.

Want Us to Email you About Special Offers & Updates?