Q.

Given below are two statements:

Statement I: Nitration of benzene involves the following step –

Statement II: Use of Lewis base promotes the electrophilic substitution of benzene.

In the light of the above statements, choose the most appropriate answer from the options given below:                [2024]

1 Statement I is correct but Statement II is incorrect  
2 Both Statement I and Statement II are correct  
3 Statement I is incorrect but Statement II is correct  
4 Both Statement I and Statement II are incorrect  

Ans.

(1)

In nitration of benzene, commonly used reagent is conc. (H2SO4+HNO3). This generates electrophile as follows:

In electrophilic substitution of benzene, Lewis acid helps in generation of electrophile, not Lewis base.