Q.

Mass of ethylene glycol (antifreeze) to be added to 18.6 kg of water to protect the freezing point at -24°C is _____ kg.

(Molar mass in g mol-1 for ethylene glycol 62, Kf of water = 1.86 K kg mol-1)               [2024]


Ans.

(15)

            Freezing point of pure water Tfo=0°C

            Freezing point of ethylene glycol solution Tf=-24°C

            Depression in freezing point, ΔTf=Tfo-Tf=0°C-(-24°C)=24°C

            Value of difference of two temperatures is same in °C and K, thus

            ΔTf=24°C or 24 K

          ΔTf=i×m×kf

          Assuming glycol to be undissociated in water, i=1

           24=1×m×1.86

          m=241.86

         WglycolMglycol×Wwater (in kg)=241.86

         Wglycol62×18.6=241.86

          Wglycol=14880g=14.88kg