Mass of ethylene glycol (antifreeze) to be added to 18.6 kg of water to protect the freezing point at -24°C is _____ kg.
(Molar mass in g mol-1 for ethylene glycol 62, Kf of water = 1.86 K kg mol-1) [2024]
(15)
Freezing point of pure water Tfo=0°C
Freezing point of ethylene glycol solution Tf=-24°C
Depression in freezing point, ΔTf=Tfo-Tf=0°C-(-24°C)=24°C
Value of difference of two temperatures is same in °C and K, thus
ΔTf=24°C or 24 K
ΔTf=i×m×kf
Assuming glycol to be undissociated in water, i=1
24=1×m×1.86
m=241.86
WglycolMglycol×Wwater (in kg)=241.86
Wglycol62×18.6=241.86
Wglycol=14880 g=14.88 kg