Q.

In Carius method of examination of halogen, 0.25 g of an organic compound gave 0.15 g of silver bromide (AgBr). The percentage of Bromine in the organic compound is _____ ×10-1 % (Nearest integer).

(Given: Molar mass of Ag is 108 and Br is 80 g mol-1)                   [2025]


Ans.

(255)

Molar mass of AgBr=(108+80)g mol-1=188g mol-1

Number of moles of AgBr (nAgBr)=Mass of AgBrMolar mass of AgBr=0.15188mol

Moles of Br=Moles of AgBr=0.15188mol

Mass of Br=Moles of Br×Molar mass of Br=0.15188×80 g

Mass % of Br=Mass of BrMass of organic compound×100

=0.15188×800.25×100=25.53%=255.3×10-1%