Q.

For a reaction N2O5(g)  2NO2(g)+12O2(g) in a constant volume container, no products were present initially. The final pressure of the system when 50% of reaction gets completed is                [2025]

1 7/4 times of initial pressure  
2 5/2 times of initial pressure  
3 5 times of initial pressure  
4 7/2 times of initial pressure  

Ans.

(1)

             N2O5(g) 2NO2(g)+12O2(g)

t=0p00t=p-0.5p2×0.5p12×0.5p=0.5p=p=0.25pTotal=1.75p=74p