Consider the following gaseous equilibrium in a closed container of volume 'V' at T(K). 2 moles each of , and are present at equilibrium. Now one mole each of and are added to the equilibrium keeping the temperature at T(K). The number of moles of

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Solution

Q.
Consider the following gaseous equilibrium in a closed container of volume 'V' at T(K).

$P_{2} (g) + Q_{2} (g) ⇌ 2 PQ (g)$

2 moles each of $P_{2} (g)$ , $Q_{2} (g)$ and $PQ (g)$ are present at equilibrium. Now one mole each of $' P_{2}'$ and $' Q_{2}'$ are added to the equilibrium keeping the temperature at T(K). The number of moles of $P_{2}$ , $Q_{2}$ and $PQ$ at the new equilibrium, respectively, are [2026]

1 2.67, 2.67, 2.67

2 1.21, 2.24, 1.56

3 1.66, 1.66, 1.66

4 2.56, 1.62, 2.24

Ans.
(1)

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