Chlorine undergoes disproportionation in alkaline medium as shown below:

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Solution

Q.
Chlorine undergoes disproportionation in alkaline medium as shown below:

${aCl}_{2 (g)} + {bOH}_{(aq)}^{-} \to {cClO}_{(aq)}^{-} + {dCl}_{(aq)}^{-} + {eH}_{2} O_{(l)}$

The values of a, b, c and d in a balanced redox reaction are respectively:

1 2, 2, 1 and 3

2 1, 2, 1 and 1

3 2, 4, 1 and 3

4 3, 4, 4 and 2

Ans.
(2)

$\overset{0}{C} l_{2} (g) + 2 {OH}^{-} (aq) \to {Cl}^{-} (aq) + \overset{+ 1}{Cl} O^{-} (aq) + H_{2} O (l)$

a = 1, b = 2, c = 1, d = 1

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