Assuming complete ionisation, same moles of which of the following compounds will require the least amount of acidified for complete oxidation? [2015]

STUDY MATERIALS
COURSES
MORE
SUCCESS STORY
ADMISSION
STORE

Back

JEE ADVANCE

CLASS XI - XII
CRASH COURSE

CLASS XI - XII

CRASH COURSE

JEE MAIN

CLASS XI - XII
CRASH COURSE

CLASS XI - XII

CRASH COURSE

NEET

CLASS XI - XII
CRASH COURSE

CLASS XI - XII

CRASH COURSE

BITSAT

CLASS XI - XII

CLASS XI - XII

CBSE BOARD

CLASS IX

CLASS X

CLASS XI

CLASS XII

CLASS VI

CLASS VII

CLASS VIII

UP BOARD

CLASS IX
CLASS X
CLASS XI
CLASS XII

CLASS IX

CLASS X

CLASS XI

CLASS XII

CUET

CRASH COURSE

CRASH COURSE

Courses

CLASSROOM COURSES
ONLINE COURSES

ONLINE COURSES

More

Solution

Q.
Assuming complete ionisation, same moles of which of the following compounds will require the least amount of acidified ${KMnO}_{4}$ for complete oxidation [2015]

1 ${FeSO}_{3}$

2 ${FeC}_{2} O_{4}$

3 $Fe {({NO}_{2})}_{2}$

4 ${FeSO}_{4}$

Ans.
(4)

${KMnO}_{4} ({Mn}^{7 +})$ changes to ${Mn}^{2 +}$ i.e., number of electrons involved per mole of ${KMnO}_{4}$ is 5.

(a) For ${FeSO}_{3}$ ,

${Fe}^{2 +} \to {Fe}^{3 +}$ (No. of $e^{-} s$ involved = 1)

${SO}_{3}^{2 -} \to {SO}_{4}^{2 -}$ (No. of $e^{-} s$ involved = 2)

Total number of $e^{-} s$ involved = 1 + 2 = 3

(b) For ${FeC}_{2} O_{4}$ ,

${Fe}^{2 +} \to {Fe}^{3 +}$ (No. of $e^{-} s$ involved = 1)

$C_{2} O_{4}^{2 -} → 2 {CO}_{2}$ (No. of $e^{-} s$ involved = 2)

Total number of $e^{-} s$ involved = 1 + 2 = 3

(c) For $Fe {({NO}_{2})}_{2}$ ,

${Fe}^{2 +} \to {Fe}^{3 +}$ (No. of $e^{-} s$ involved = 1)

$2 {NO}_{2}^{-} → 2 {NO}_{3}^{-}$ (No. of $e^{-} s$ involved = 4)

Total number of $e^{-} s$ involved = 1 + 4 = 5

(d) For ${FeSO}_{4}$ ,

${Fe}^{2 +} {\to Fe}^{3 +}$ (No. of $e^{-} s$ involved = 1)

Total number of $e^{-} s$ involved = 1

As ${FeSO}_{4}$ requires the least number of electrons, thus, it will require the least amount of ${KMnO}_{4}$ .

Want Us to Email you About Special Offers & Updates?