Q.

Given below are two statements : One is labelled as Assertion A and the other is labelled as Reason R:

Assertion A : A reaction can have zero activation energy.

Reason R : The minimum extra amount of energy absorbed by reactant molecules so that their energy becomes equal to threshold value, is called activation energy.

In the light of the above statements, choose the correct answer from the options given below.               [2023]

1 A is true but R is false.  
2 A is false but R is true.  
3 Both A and R are true and R is the correct explanation of A.  
4 Both A and R are true and R is not the correct explanation of A.  

Ans.

(2)

If Ea=0, then according to Arrhenius equation,  k=Ae-Ea/RTk=Ae0/RT=A.

This implies that every collision results into a chemical reaction which cannot be true. So, a reaction cannot have zero activation energy.