Q.

An organic compound contains 78% (by wt) carbon and remaining percentage of hydrogen. The right option for the empirical formula of this compound is [Atomic wt. of C is 12, H is 1]                    [2021]

1 CH4  
2 CH  
3 CH2  
4 CH3  

Ans.

(4)

Given percentage of carbon - 78% and hence percentage of hydrogen - 22%.

Element % Relative number of atoms Simplest ratio
Carbon 78 7812=6.5 6.56.5=1
Hydrogen 22 221=22 226.5=3.33


   Empirical formula = CH3