Q.

Among CrOCr2O3 and CrO3, the sum of spin-only magnetic moment values of basic and amphoteric oxides is _______ 10-2 BM (nearest integer).

(Given atomic number of Cr is 24)                      [2024]


Ans.

(877)

Oxide Nature Electronic
configuration of
central metal ion
Number
of unpaired
electrons
(n)
Spin only
magnetic
moment (μ) =n(n+2)BM
CrO Basic Cr+2=[Ar]183d44s0          4 4(4+2)BM=4.9 BM
Cr2O3 Amphoteric Cr+3=[Ar]183d34s0          3 3(3+2)BM=3.87 BM
CrO3 Acidic Cr+6=[Ar]183d04s0          0                     0

Sum = 4.9 + 3.87 = 8.77 = 877 ×10-2