Q.

A sample of a metal oxide has formula M0.83O1.00. The metal M can exist in two oxidation states +2 and +3. In the sample of M0.83O1.00, the percentage of metal ions existing in +2 oxidation state is _______ % (nearest integer).                   [2023]


Ans.

(59)

Let no. of ions of M+2=x

M+3=0.83-x

2x+3(0.83-x)+1(-2)=0

2x+2.49-3x-2=0

x=0.49

% M2+ ions=0.490.83×100=59.03