Q 11 :    

Two different adiabatic paths for the same gas intersect two isothermal curves as shown in P - V diagram. The relation between the ratio VaVd and the ratio VbVc is      [2024]

  • VaVd=VbVc

     

  • VaVdVbVc

     

  • VaVd=(VbVc)2

     

  • VaVd=(VbVc)-1

     

(1)

For adiabatic process

TVγ-1=constant

Ta·Vaγ-1=Td·Vγ-1

(VaVd)γ-1=TdTa                                 ...(i)

Tb·Vbγ-1=Tc·Vcγ-1

(VbVc)γ-1=TcTb                           ...(ii)

As, Td=Tc and Ta=TbVaVd=VbVc



Q 12 :    

A real gas within a closed chamber at 27°C undergoes the cyclic process as shown in figure. The gas obeys PV3=RT equation for the path A to B. The net work done in the complete cycle is (assuming R = 8 J/mol K)             [2024]

  • 225 J

     

  • 205 J

     

  • 20 J

     

  • - 20 J

     

(2)

For A to B:

Given PV3=RTP=RTV3

Work done WAB=PdV

WAB=RTV3dV=RT[V-2-2]VA=2VB=4

=-RT2[1V2]=-RT2[116-14]

=-RT2(-316)=3RT32

WAB=332×8×300=225 J

WBC (Isobaric process)

WBC=PΔV=10(2-4)=-20 J

WAC (Isochoric process) = 0

Wnet=WAB+WBC+WCA=225-20+0=205 J



Q 13 :    

A thermodynamic system is taken from an original state A to an intermediate state B by a linear process as shown in the figure. Its volume is then reduced to the original value from B to C by an isobaric process. The total work done by the gas from A to B and B to C would be          [2024]

  • 33800 J

     

  • 2200 J

     

  • 800 J

     

  • 1200 J

     

(3)

Work done AB=12(8000+4000) Dyne/cm2×4 m3

                          =(6000 Dyne/cm2)×4 m3

Work done BC=(4000 Dyne/cm2)×4 m3

Total work done =2000 Dyne/cm2×4 m3

         =2×103×1105Ncm2×4 m3

         =2×10-2×N10-4 m2×4 m3

          =2×102×4 Nm=800 J



Q 14 :    

Choose the correct statement for processes A and B shown in figure.               [2024]

  • PVγ=k for process B and PV=k for process A.

     

  • PV=k for process B and A.

     

  • Pγ1/Tγ=k for process B and 𝑇=𝑘 for process A.

     

  • Tγ/Pγ1=k for process A and PV=k for process B.

     

(1)

Slope of isothermal < Slope of adiabatic

(Slope)A<(Slope)B

Process B  adiabatic  PVγ=K

Process A isothermalPV=K