Q 1 :    

Among the given compounds I–III, the correct order of bond dissociation energy of C—H bond marked with * is      [2025]

[IMAGE 9]

  • III > II > I

     

  • II > III > I

     

  • II > I > III

     

  • I > II > III

     

(3)

 



Q 2 :    

Which of the following molecules has ''non zero'' dipole moment value?             [2024]

  • CCl4

     

  • HI

     

  • CO2

     

  • BF3

     

(2)

[IMAGE 10]

 



Q 3 :    

Match List-I with List-II.                                                                 [2024]

  List-I   List-II
  (Molecule)   [Bond enthalpy (kJ mol-1)]
A. HCl I. 435.8
B. N2 II. 498
C. H2 III. 946.0
D. O2 IV. 431.0

 

Choose the correct answer from the options given below.

  • A – III, B – IV, C – I, D – II

     

  • A – IV, B – I, C – III, D – II

     

  • A – IV, B – III, C – II, D – I

     

  • A – IV, B – III, C – I, D – II

     

(4)

Molecule Bond enthalpy (kJ mol-1)
HCl 431.0
N2 946.0
H2 435.8
O2 498

 



Q 4 :    

Identify the correct answer.                                     [2024]

  • Three resonance structures can be drawn for ozone.

     

  • BF3 has non-zero dipole moment.

     

  • Dipole moment of NF3 is greater than that of NH3.

     

  • Three canonical forms can be drawn for CO32- ion.

     

(4)

[IMAGE 11]----------------------

F is more electronegative than H, the resultant dipole moment of NH3 is much more than that of NF3 due to its resultant dipole moment.

[IMAGE 12]-------------

[IMAGE 13]----------------
 

 



Q 5 :    

The correct order of dipole moments for molecules NH3,H2S,CH4 and HF, is                     [2023]

  • CH4>H2S>NH3>HF

     

  • H2S>NH3>HF>CH4

     

  • NH3>HF>CH4>H2S

     

  • HF>NH3>H2S>CH4 

     

(4)

A given molecule posses dipole moment as a result of polarisation. Polarisation arises in a heteronuclear molecule due to significant electronegativity difference between atoms involved in covalent bond formation. The shared electron pair gets displaced towards more electronegative atom and the resultant covalent bond is polar covalent bond.

Thus, the correct order is: HF>NH3>H2S>CH4(Non-polar)



Q 6 :    

Which of the following molecules is non-polar in nature?                 [2021]

  • NO2

     

  • POCl3

     

  • CH2O

     

  • SbCl5

     

(4)

Among the given molecule of SbCl5 is non-polar in nature.
 

 



Q 7 :    

Which of the following set of molecules will have zero dipole moment?             [2020]

  • Ammonia, beryllium difluoride, water, 1,4-dichlorobenzene

     

  • Boron trifluoride, hydrogen fluoride, carbon dioxide, 1,3-dichlorobenzene

     

  • Nitrogen trifluoride, beryllium difluoride, water, 1,3-dichlorobenzene

     

  • Boron trifluoride, beryllium difluoride, carbon dioxide, 1,4-dichlorobenzene 

     

(4)

[IMAGE 14]

 



Q 8 :    

Which of the following is the correct order of dipole moment?      [2019]

  • NH3<BF3<NF3<H2O

     

  • BF3<NF3<NH3<H2O

     

  • BF3<NH3<NF3<H2O 

     

  • H2O<NF3<NH3<BF3

     

(2)

[IMAGE 15]

 



Q 9 :    

The species, having bond angles of 120° is                  [2017]   

  • ClF3

     

  • NCl3

     

  • BCl3

     

  • PH3

     

(3)

BCl3- Trigonal planar, sp2-hybridised, 120° angle.
 

 



Q 10 :    

Consider the molecules CH4, NH3 and H2O. Which of the given statements is false?         [2016]

  • The H—O—H bond angle in H2O is smaller than the H—N—H bond angle in NH3.

     

  • The H—C—H bond angle in CH4 is larger than the H—N—H bond angle in NH3.

     

  • The H—C—H bond angle in CH4, the H—N—H bond angle in NH3 and the H—O—H bond angle in H2O are all greater than 90°.

     

  • The H—O—H bond angle in H2O is larger than the H—C—H bond angle in CH4.

     

(4)

[IMAGE 16]