Q 1 :    

The standard heat of formation in kcal/mol of Ba2+ is

Given: standard heat of formation of SO42- ion(aq) = -216 kcal/mol, standard heat of crystallisation of BaSO4(s)=-4.5 kcal/mol, standard heat of formation of BaSO4(s)=-349 kcal/mol.                         [2025]

  • +133.0

     

  • +220.5

     

  • -128.5

     

  • -133.0

     

(3)

ΔHf(BaSO4)=ΔHf(Ba2+)+ΔHf(SO42-)+ΔHcrys.(BaSO4)

ΔHf(Ba2+)=ΔHf(BaSO4)-ΔHf(SO42-)-ΔHcrys.(BaSO4)

ΔHf(Ba2+)=-349+216+4.5kcal/mol

                     =-128.5 kcal/mol



Q 2 :    

Consider the following reaction:  

2H2(g)+O2(g)2H2O(g);  ΔrH°=-483.64 kJ

What is the enthalpy change for decomposition of one mole of water? (Choose the right option.)         [2023]

  • 120.9 kJ

     

  • 241.82 kJ

     

  • 18 k]

     

  • 100 kJ

     

(2)

Decomposition for 1 mole of water,

H2O(g)H2(g)+12O2(g);H=+483.64kJ2

ΔH=+241.82 kJ mol-1