Q 1 :    

Which of the following is incorrect statement?                [2019]

  • SnF4 is ionic in nature.

     

  • PbF4 is covalent in nature.

     

  • SiCl4 is easily hydrolysed.

     

  • GeX4 (X=F,Cl,Br,I) is more stable than GeX2.

     

(2)

Generally, the halides of group-14 elements are covalent in nature. PbF4 and SnF4 are exceptions which are ionic in nature.

 



Q 2 :    

Which of the following species is not stable?            [2019]

  • [SiCl6]2-

     

  • [SiF6]2-

     

  • [GeCl6]2-

     

  • [Sn(OH)6]2-

     

(1)

[SiCl6]2- is not stable due to steric hindrance by large sized Cl atoms.
 

 



Q 3 :    

It is because of inability of ns2 electrons of the valence shell to participate in bonding that                 [2017]

  • Sn2+ is oxidising while Pb4+ is reducing

     

  • Sn2+ and Pb2+ are both oxidising and reducing

     

  • Sn4+ is reducing while Pb4+ is oxidising

     

  • Sn2+ is reducing while Pb4+ is oxidising

     

(4)

The inertness of s-subshell electrons towards bond formation is known as inert pair effect. This effect increases down the group thus, for Sn, +4 oxidation state is more stable, whereas, for Pb, +2 oxidation state is more stable, i.e., Sn2+ is reducing while Pb4+ is oxidising.