Q 1 :    

Select the element (M) whose trihalides cannot be hydrolysed to produce an ion of the form [M(H2O)6]3+.            [2023]
 

  • Ga

     

  • In

     

  • Al

     

  • B

     

(4)

Maximum covalency of boron is four due to the absence of d-orbitals. Hence, its trihalide cannot be hydrolysed to produce an ion of the form [M(H2O)6]3+.

 



Q 2 :    

Which one of the following elements is unable to form MF63- ion?                 [2018]

  • Ga

     

  • Al

     

  • B

     

  • In

     

(3)

Boron does not have vacant d-orbitals in its valence shell, so it cannot expand its covalency beyond 4 i.e., 'B' cannot form the ions like MF63-.