Q 1 :    

Taking stability as the factor, which one of the following represents correct relationship?           [2023]
 

  • AlCl>AlCl3

     

  • TlI>TlI3

     

  • TlCl3>TlCl

     

  • InI3>InI

     

(2)

As we move down the group, the stability of the +3 oxidation state decreases while that of +1 oxidation state increases. Thus, stability order for +1 oxidation state is Al<Ga<In<Tl and +3 oxidation state is Al>Ga>In>Tl.

Hence, the stability order is, AlCl3>AlCl, TlI>TlI3, TlCl>TlCl3 and InI>InI3.

 



Q 2 :    

BF3 is planar and electron deficient compound. Hybridization and number of electrons around the central atom, respectively are           [2021]
 

  • sp2 and 8

     

  • sp3 and 4

     

  • sp3 and 6

     

  • sp2 and 6

     

(4)

BF3 is a sp2-hybridised planar molecule. It forms 3σ-bonds with 3F-atoms, hence has six electrons around it.



Q 3 :    

The correct order of atomic radii in group 13 elements is            [2018]

  • B<Al<In<Ga<Tl

     

  • B<Al<Ga<In<Tl

     

  • B<Ga<Al<Tl<In

     

  • B<Ga<Al<In<Tl

     

(4)

 



Q 4 :    

The stability of +1 oxidation state among Al, Ga, In and Tl increases in the sequence              [2015, 2009]

  • Al<Ga<In<Tl

     

  • Tl<In<Ga<Al

     

  • In<Tl<Ga<Al

     

  • Ga<In<Al<Tl

     

(1)

In group 13 elements, stability of +3 oxidation state decreases down the group while that of +1 oxidation state increases due to inert pair effect. Hence, stability of +1 oxidation state increases in the sequence: Al<Ga<In<Tl.