Q 11 :    

For the redox reaction,

MnO4-+C2O42-+H+Mn2++CO2+H2O

The correct coefficients of the reactants for the balanced equation are:                  [2018]

  • MnO4--16,     C2O42--5,     H+-2

     

  • MnO4--2,     C2O42--5,     H+-16

     

  • MnO4--2,     C2O42--16,     H+-5

     

  • MnO4--5,     C2O42--16,     H+-2

     

(2)

The correct balanced equation is  

2MnO4-+5C2O42-+16H+2Mn2++10CO2+8H2O



Q 12 :    

Hot concentrated sulphuric acid is a moderately strong oxidizing agent. Which of the following reactions does not show oxidizing behaviour?           [2016]

  • Cu+2H2SO4CuSO4+SO2+2H2O

     

  • S+2H2SO43SO2+2H2O

     

  • C+2H2SO4CO2+2SO2+2H2O

     

  • CaF2+H2SO4CaSO4+2HF  

     

(4)

CaF2+H2SO4CaSO4+2HF

Here, the oxidation state of every atom remains the same, so it is not a redox reaction.



Q 13 :    

(I)   H2O2+O3H2O+2O2

(II)   H2O2+Ag2O2Ag+H2O+O2

Role of hydrogen peroxide in the above reactions is respectively             [2014]

  • oxidizing in (I) and reducing in (II)

     

  • reducing in (I) and oxidizing in (II)

     

  • reducing in (I) and (II)

     

  • oxidizing in (I) and (II)

     

(3)

[IMAGE 41]

[IMAGE 42]

H2O2 acts as reducing agent in both the reactions in which O2 is evolved. 



Q 14 :    

The pair of compounds that can exist together is                [2014]

  • FeCl3, SnCl2

     

  • HgCl2, SnCl2

     

  • FeCl2, SnCl2

     

  • FeCl3, KI

     

(3)

Both FeCl2 and SnCl2 are reducing agents with low oxidation numbers.