Q 1 :    

Ethylene diaminetetraacetate ion is a/an              [2024]

  • hexadentate ligand

     

  • ambidentate ligand

     

  • monodentate ligand

     

  • bidentate ligand

     

(1)

Ethylene diamine tetraacetate ion (EDTA4-) is an important hexadentate ligand. It can bind through two nitrogen and four oxygen atoms to a central metal ion.

 



Q 2 :    

Which of the following is not an ambidentate ligand?            [2024]

  • C2O42-

     

  • SCN-

     

  • NO2-

     

  • CN-

     

(1)

The oxalate (C2O42-) ligand is said to be a didentate ligand as it can bind through two donor atoms.
 

 



Q 3 :    

Given below are two statements :  

Statement I [Co(NH3)6]3+ is a homoleptic complex whereas [Co(NH3)4Cl2]+ is a heteroleptic complex.  

Statement II : Complex [Co(NH3)6]3+ has only one kind of ligands but [Co(NH3)4Cl2]+ has more than one kind of ligands.  

In the light of the above statements, choose the correct answer from the options given below:                     [2024]

  • Both Statement I and Statement II are true.

     

  • Both Statement I and Statement II are false.  

     

  • Statement I is true and Statement II is false.

     

  • Statement I is false and Statement II is true.

     

(1)

Complexes in which a metal is bound to only one kind of donor groups e.g., [Co(NH3)6]3+ are known as homoleptic. Complexes in which a metal is bound to more than one kind of donor groups, e.g., [Co(NH3)4Cl2]+ are known as heteroleptic.

 



Q 4 :    

Which complex compound is most stable?               [2023]

  • [CoCl2(en)2]NO3

     

  • [Co(NH3)6]2(SO4)3

     

  • [Co(NH3)4(H2O)Br](NO3)2

     

  • [Co(NH3)3(NO3)3]

     

(1)

Chelating ligands (e.g., en) form more stable complexes than unidentate ligands.

 



Q 5 :    

Ethylene diaminetetraacetate (EDTA) ion is              [2021]

  • tridentate ligand with three "N" donor atoms

     

  • hexadentate ligand with four "O" and two "N" donor atoms

     

  • unidentate ligand

     

  • bidentate ligand with two "N" donor atoms.

     

(2)

Ethylenediaminetetraacetate ion (EDTA4-) is an important hexadentate ligand. It can bind through two nitrogen and four oxygen atoms to a central metal ion.

 



Q 6 :    

The correct increasing order of trans-effect of the following species is                [2016]

  • NH3>CN->Br->C6H5-

     

  • CN->C6H5->Br->NH3

     

  • Br->CN->NH3>C6H5-

     

  • CN->Br->C6H5->NH3

     

(2)

The intensity of the trans-effect (as measured by the increase in rate of substitution of the trans ligand) follows the sequence: 
CN->C6H5->Br->NH3

 



Q 7 :    

The sum of coordination number and oxidation number of the metal M in the complex [M(en)2(C2O4)]Cl (where en is ethylenediamine) is          [2015]

  • 6

     

  • 7

     

  • 8

     

  • 9

     

(4)

[M(en)2(C2O4)]Cl

Oxidation number of metal = +3

Coordination number of metal = 6

Sum of oxidation number and coordination number = 3 + 6 = 9