Ethylene diaminetetraacetate ion is a/an [2024]
hexadentate ligand
ambidentate ligand
monodentate ligand
bidentate ligand
(1)
Ethylene diamine tetraacetate ion is an important hexadentate ligand. It can bind through two nitrogen and four oxygen atoms to a central metal ion.
Which of the following is not an ambidentate ligand? [2024]
(1)
The oxalate ligand is said to be a didentate ligand as it can bind through two donor atoms.
Given below are two statements :
Statement I : is a homoleptic complex whereas is a heteroleptic complex.
Statement II : Complex has only one kind of ligands but has more than one kind of ligands.
In the light of the above statements, choose the correct answer from the options given below: [2024]
Both Statement I and Statement II are true.
Both Statement I and Statement II are false.
Statement I is true and Statement II is false.
Statement I is false and Statement II is true.
(1)
Complexes in which a metal is bound to only one kind of donor groups e.g., are known as homoleptic. Complexes in which a metal is bound to more than one kind of donor groups, e.g., are known as heteroleptic.
Which complex compound is most stable? [2023]
(1)
Chelating ligands (e.g., en) form more stable complexes than unidentate ligands.
Ethylene diaminetetraacetate (EDTA) ion is [2021]
tridentate ligand with three "N" donor atoms
hexadentate ligand with four "O" and two "N" donor atoms
unidentate ligand
bidentate ligand with two "N" donor atoms.
(2)
Ethylenediaminetetraacetate ion is an important hexadentate ligand. It can bind through two nitrogen and four oxygen atoms to a central metal ion.
The correct increasing order of trans-effect of the following species is [2016]
(2)
The intensity of the trans-effect (as measured by the increase in rate of substitution of the trans ligand) follows the sequence:
The sum of coordination number and oxidation number of the metal in the complex (where is ethylenediamine) is [2015]
6
7
8
9
(4)
:
Oxidation number of metal = +3
Coordination number of metal = 6
Sum of oxidation number and coordination number = 3 + 6 = 9