Q 21 :    

Consider the Bohr model of hydrogen like atoms, the ratio of the radius of 5th orbit of the electron in Li2+ and He+ is          [2025]

  • 32

     

  • 49

     

  • 94

     

  • 23

     

(4)

r=a0·n2Z

For Li2+r5=a0·253

for He+r5=a0·252

  rLi2+rHe+=23



Q 22 :    

Given below are two statements:

Statement (I) : The dimensions of Planck's constant and angular momentum are same.

Statement (II) : In Bhor's model electron revolve around the nucleus only in those orbits for which angular momentum is integral multiple of Planck's constant.

In the light of the above statements, choose the most appropriate answer from the options given below:          [2025]

  • Both Statemen I and Statement II are correct.

     

  • Statement I is incorrect but State II is correct.

     

  • Statement I is correct but State II is incorrect.

     

  • Both Statemen I and Statement II are incorrect.

     

(3)

E = hf

ML2T2=[h]×[T1]

[h]=[ML2T1]

L=[MVR]=[ML2T1]

L=nh2π

L is integral multiple of h2π



Q 23 :    

In a hydrogen like ion, the energy difference between the 2nd excitation energy state and ground is 108.8 eV. The atomic number of the ion is         [2025]

  • 4

     

  • 2

     

  • 1

     

  • 3

     

(4)

E=13.6Z2[1n121n22]

13.6Z2[1119]=108.8

13.6×89(Z2)=108.8  Z=3



Q 24 :    

An electron in the hydrogen atom initially in the fourth excited state makes a transition to n energy state by emitting a photon of energy 2.86 eV. The integer value of n will be ________.          [2025]



2

E=13.6(1n121n12)

2.86=13.6(1n2152)

1n2=0.21+125

n2=4  n=2