Q 1 :    

Choose the polar molecule from the following.               [2024]

  • CCl4

     

  • CO2

     

  • CH2=CH2

     

  • CHCl3

     

(4)

In CCl4, CO2 and CH2=CH2, individual bond moments cancel out to give a net zero dipole moment. In CHCl3, because it is not a symmetrical molecule, vector sum of bond moments is not zero i.e. it is a polar molecule.

 



Q 2 :    

Given below are two statements:

Statement - I: Since Fluorine is more electronegative than nitrogen, the net dipole moment of NF3 is greater than NH3.

Statement - II: In NH3, the orbital dipole due to lone pair and the dipole moment of NH bonds are in opposite direction, but in NF3 the orbital dipole due to lone pair and dipole moments of N-F bonds are in same direction.

In the light of the above statements, choose the most appropriate from the options given below:          [2024]

  • Statement I is true but Statement II is false.

     

  • Both Statement I and Statement II are false.

     

  • Both Statement I and Statement II are true.

     

  • Statement I is false but Statement II is true.

     

(2)

In NF3, lone pair moment and bond pair moments are in opposite direction but in NH3, lone pair moment and bond pair moments are in same direction. Hence resultant dipole moment in NH3 is more.

 

 



Q 3 :    

Number of molecules/ions from the following in which the central atom is involved in sp3 hybridization is ________.

NO3-,BCl3,ClO2-,ClO3                      [2024]

  • 3

     

  • 2

     

  • 1

     

  • 4

     

(2)

 



Q 4 :    

The number of species from the following that have pyramidal geometry around the central atom is ________.

S2O32-,SO42-,SO32-,S2O72-                      [2024]

  • 1

     

  • 2

     

  • 3

     

  • 4

     

(1)

 



Q 5 :    

Match List-I with List-II.

  List-I   List-II
A. ICl I. T-shape
B. ICl3 II. Square pyramidal
C. ClF5 III. Pentagonal bipyramidal
D. IF7 IV. Linear

 

Choose the correct answer from the options given below:                  [2024]

  • (A)–(IV), (B)–(I), (C)–(II), (D)–(III)

     

  • (A)–(I), (B)–(IV), (C)–(III), (D)–(II)

     

  • (A)–(I), (B)–(III), (C)–(II), (D)–(IV)

     

  • (A)–(IV), (B)–(III), (C)–(II), (D)–(I)

     

(1)

 



Q 6 :    

Match List I with List II

  List I (Molecular/Species)   List II (Property/Shape)
A. SO2Cl2 I. Paramagnetic
B. NO II. Diamagnetic
C. NO2- III. Tetrahedral
D. I3- IV. Linear

 

Choose the correct answer from the options given below:                                          [2024]

  • A–III, B–IV, C–II, D–I

     

  • A–IV, B–I, C–III, D–II

     

  • A–II, B–III, C–I, D–IV

     

  • A–III, B–I, C–II, D–IV

     

(4)

 



Q 7 :    

Match List I with List II.

  List I (Hybridization)   List II (Orientation in Space)
A. sp3 I. Trigonal bipyramidal
B. dsp2 II. Octahedral
C. sp3d III. Tetrahedral
D. sp3d2 IV. Square planar

 

Choose the correct answer from the options given below:                      [2024]

  • A–IV, B–III, C–I, D–II

     

  • A–II, B–I, C–IV, D–III

     

  • A–III, B–IV, C–I, D–II

     

  • A–III, B–I, C–IV, D–II

     

(3)

 



Q 8 :    

Match List I with List II

  List I (Compound/Species)   List II (Shape/Geometry)
A. SF4 I. Tetrahedral
B. BrF3 II. Pyramidal
C. BrO3- III. See Saw
D. NH4+ IV. Bent T-Shape

 

Choose the correct answer from the options given below:                   [2024]

  • A–III, B–II, C–IV, D–I

     

  • A–II, B–IV, C–III, D–I

     

  • A–II, B–III, C–I, D–IV

     

  • A–III, B–IV, C–II, D–I

     

(4)

 



Q 9 :    

Match List I with List II

  List I (Molecule)   List II (Shape)
A. NH3 I. Square pyramidal
B. BrF5 II. Tetrahedral
C. PCl5 III. Trigonal pyramidal
D. CH4 IV. Trigonal bipyramidal

 

Choose the correct answer from the options given below:                  [2024]

  • A–IV, B–III, C–I, D–II

     

  • A–II, B–IV, C–I, D–III

     

  • A–III, B–IV, C–I, D–II

     

  • A–III, B–I, C–IV, D–II

     

(4)

 



Q 10 :    

In which one of the following pairs the central atoms exhibit sp2 hybridization?            [2024]

  • NH2- and BF3

     

  • NH2- and H2O

     

  • BF3 and NO2-

     

  • H2O and NO2

     

(3)