Q 1 :    

Sugar which does not give reddish brown precipitate with Fehling’s reagent, is:              [2024]

  • Sucrose

     

  • Lactose

     

  • Glucose

     

  • Maltose

     

(A)

Sucrose does not have an aldehydic or ketonic group. Hence sucrose is a non-reducing sugar and does not give reddish brown precipitate with Fehling’s reagent. All monosaccharides (such as glucose) are reducing sugars.

 



Q 2 :    

Match List I with List II

  List I   List II
A. α-Glucose and α-Galactose I. Functional isomers
B. α-Glucose and β-Glucose II. Homologous
C. α-Glucose and α-Fructose III. Anomers
D. α-Glucose and α-Ribose IV. Epimers

 

Choose the correct answer from the options given below:              [2024]

  • A-III, B-IV, C-II, D-I

     

  • A-III, B-IV, C-I, D-II

     

  • A-IV, B-III, C-II, D-I

     

  • A-IV, B-III, C-I, D-II

     

(D)

    A. Epimers are diastereomers that differ in configuration at only one chiral centre. α-Glucose and α-Galactose are C-4 epimers.

   B. Anomers are epimers which differ in configuration at acetal or hemiacetal carbon. α-D-glucose and β-D-glucose are anomers.

   C. Glucose is an aldohexose and fructose is a ketohexose. These are thus functional isomers.

   D. Formula of glucose (C6H12O6) differs by — CH2 unit with the formula of ribose (C5H10O5). So, Homologns



Q 3 :    

The incorrect statement about Glucose is:                   [2024]

  • Glucose remains in multiple isomeric form in its aqueous solution

     

  • Glucose is one of the monomer unit in sucrose

     

  • Glucose is an aldohexose

     

  • Glucose is soluble in water because of having aldehyde functional group.

     

(D)

        1.  Glucose exists as equilibrium mixture of α-D-glucose, open chain structure and β-D-glucose.

        2.  Sucrose is a disaccharide formed by glycosidic linkage between C1 of α-D-glucose and C2 of β-D-fructose.

        3.  Glucose is an aldohexose.

        4.  Water solubility of glucose is because it forms extensive hydrogen bonding with water.